The synergistic effects of niobium and molybdenum in lowering austenite-to-ferrite transformation temperatures have been known for approximately 45 years. The benefits have been widely exploited in linepipe steels since 1971 when 485 MPa (X70) linepipe produced by IPSCO  was installed in Canada in the TransCanada and Novacorp gas transmission systems. At that time the steels were cast as semi-killed ingots and had inferior transverse Charpy properties due to the presence of MnS and silicate inclusions. Other applications have been found in hot-rolled long products  and Nippon Steel’s HT80 quenched and tempered plate [3,4]. As linepipe yield strengths have increased to X80, X100 and above, and carbon contents have been reduced to 0.03-0.06 percent, the Nb-Mo combination has become indispensable for producing economical steels when used in combination with chromium, copper and nickel. This paper provides a brief chronology of the adoption of Nb-Mo and Nb-Mo-B alloying since the mid 1960s. (AU) Copyright © 2014 Companhia Brasileira de Metalurgia e Mineração (CBMM) All rights reserved.
Technical Paper (PDF 1.91 MB)